Chung-Ang University Develops Chloride-Resistant Ru Nanocatalysts for Sustainable Hydrogen Production from Seawater

A breakthrough in sustainable hydrogen generation from natural resources

SEOUL, South Korea, Sept. 18, 2025 /PRNewswire/ -- Growing global demand for clean energy and climate change concerns have intensified the search for sustainable alternatives. Hydrogen emerges as a promising solution due to its high energy density and zero-carbon emissions. Among production methods, alkaline water electrolysis is efficient and environmentally friendly; however, its dependence on freshwater limits large-scale implementation. Seawater electrolysis offers a practical alternative by tapping Earth's abundant water resources, but high chloride concentrations accelerate catalyst corrosion and reduce efficiency, posing significant challenges for sustainable hydrogen generation.

To address this, a research team led by Assistant Professor Haeseong Jang at Chung-Ang University and Professor Xien Liu at Qingdao University of Science and Technology, developed a robust and cost-effective electrocatalyst capable of high-performance hydrogen evolution in saline environments. Dr. Jang shares the motivation behind this study: "Alkaline water electrolysis, though economically attractive due to inexpensive non-precious metal catalysts, faces significant challenges, including slow hydrogen evolution reaction (HER) kinetics and corrosion problems in real-world environments that hinder commercialization. Our research is driven by the mission to develop economically viable and stable clean hydrogen production technology to overcome these critical barriers." Their findings were made available online in Advanced Functional Materials on August 7, 2025.

They designed a ruthenium (Ru)-based catalyst that overcomes limitations of conventional platinum or Ru catalysts in alkaline and seawater electrolysis. They employed a g-C₃N₄-mediated pyrolysis strategy to synthesize nitrogen-doped carbon-supported Ru nanoclusters with a crystalline–amorphous heterostructure (a/c-Ru@NC). g-C₃N₄ serves as a nitrogen source and a scaffold that anchors Ru³⁺ ions through N-coordination sites. During pyrolysis, reductive gases released from g-C₃N₄ reduce Ru³⁺ in situ, while Ru–N bonding disrupts atomic order in the core, forming an amorphous Ru phase. Surface Ru atoms simultaneously crystallize, producing a stable crystalline–amorphous junction. This architecture ensures ultrafine Ru dispersion, electron-deficient active sites, and compressive lattice strain.

Electrochemical testing demonstrated outstanding HER performance. In 1.0 M KOH, a/c-Ru@NC exhibited an overpotential of just 15 mV at 10 mA cm⁻². Durability was confirmed with stable operation over 250 hours. Crucially, the catalyst exhibited exceptional chloride corrosion resistance with only 8 mV performance degradation and stable operation over 100 hours in simulated seawater, outperforming commercial Pt/C and Ru/C.

The study highlights several advantages. The a/c-Ru@NC synergistically combines abundant active sites with optimized electron transport. The nitrogen-doped carbon support prevents Ru oxidation and agglomeration. The overall design provides exceptional chloride-corrosion resistance. Together, these features enable cost-effective, scalable hydrogen production directly from seawater. This approach reduces reliance on freshwater and fossil fuels while supporting decarbonization across energy-intensive sectors.

Prof. Liu emphasizes, "Our breakthrough enables seawater electrolysis for direct hydrogen production from seawater using chloride-resistant catalysts, opening up vast oceanic resources for clean energy generation." He adds, "The enhanced alkaline water electrolysis systems demonstrate remarkable economic viability with 37-fold higher mass activity compared to commercial Pt catalysts, making hydrogen production significantly more cost-effective."

In conclusion, this work establishes a g-C₃N₄-mediated heterostructuring strategy that simultaneously addresses activity, stability, and corrosion challenges in Ru-based electrocatalysts. Dr. Jang notes, "Our technology will accelerate climate change mitigation efforts by enabling rapid decarbonization of transportation, industrial, and power generation sectors." By enabling efficient and durable seawater electrolysis, this study provides a blueprint for sustainable hydrogen generation from oceanic resources, paving the way for large-scale, green hydrogen infrastructure.

Reference

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